
Cavansite, whose name is derived from its chemical composition, calcium vanadium silicate, is a deep blue hydrous calcium vanadium phyllosilicate mineral, occurring as a secondary mineral in basaltic and andesitic rocks along with a variety of zeolite minerals. Discovered in 1967 in Malheur County, Oregon, cavansite is a relatively rare mineral. It is polymorphic with the even rarer mineral, pentagonite. It is most frequently found in Pune, India and in the Deccan Traps, a large igneous province.

Mathesiusite is a sulfate mineral containing potassium, vanadium, and uranium and has the chemical formula: K5(UO2)4(SO4)4(VO5)·4(H2O). It is a secondary mineral formed during post-mining processes.

Paramontroseite (V4+O2) is a relatively rare orthorhombic vanadium oxide mineral in the Ramsdellite group. Synthetic paramontroseite may have applications in medicine, batteries and electronics.

Patronite is the vanadium sulfide mineral with formula VS4. The material is usually described as V4+(S22−)2. Structurally, it is a "linear-chain" compound with alternating bonding and nonbonding contacts between the vanadium centers. The vanadium is octa-coordinated, which is an uncommon geometry for this metal.

Pentagonite is a rare silicate mineral with formula Ca(VO)Si4O10·4(H2O). It was named for the unusual twinning which produces an apparent five-fold symmetry. It is a dimorph of cavansite.

Roscoelite is a green mineral from the mica group that contains vanadium.

Sincosite is a green mineral discovered in 1922. It is named for Sincos, Daniel Alcides Carrión Province, Peru, where it was first discovered.