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Thomas Brigstocke was a Welsh portrait painter. He studied art in London, and then spent eight years in Italy before returning to England. In the 1840s he visited Egypt, where he painted portraits of Mohammed Ali Pasha and his family.

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John Downman was a Welsh portrait and subject painter.

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David Griffiths, is a Welsh portrait painter.

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George Frederick Harris (1856–1924) was a Welsh portrait and landscape painter.

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Gwendolen Mary John was a Welsh artist who worked in France for most of her career. Her paintings, mainly portraits of anonymous female sitters, are rendered in a range of closely related tones. Although she was overshadowed during her lifetime by her brother Augustus John and her lover Auguste Rodin, her reputation has grown steadily since her death.

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Barnett Samuel Marks R.C.A. was a Welsh-Jewish portrait painter who was also noted for his social realism paintings.

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Edward Owen was a Welsh artist; the son of minor nobility from Penrhos on Anglesey, who held an apprenticeship in London with the artist Thomas Gibson.

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John Cambrian Rowland was a Welsh painter.

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Thomas Edgar Stephens was a Welsh-American artist and portrait painter.

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Andrew Vicari was a Welsh painter working in France, who established a career painting portraits of prominent people. Despite being largely unknown in his own country, as of 2004 Vicari was Britain's richest living painter, and at one time Britain's 18th richest person.

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Margaret Lindsay Williams, was a Welsh artist who was commissioned to paint portraits of the British royal family, European royalty and American presidents. She was best known as a portrait painter and painted portraits of Queen Alexandra, Queen Mary, Princess Margaret and at least five portraits of the present Queen Elizabeth II. She also painted President Warren Harding, Henry Ford and Field Marshal Slim. Although Williams gained considerable recognition and was famous in her lifetime, her work has been neglected since.

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Nathan Wyburn is a Welsh artist and media personality who has created celebrity portraits and pop culture imagery using non-traditional media such as foodstuffs and other household items, most notably working with Marmite on toast. He has personally created works of art for such notable subjects as Madonna, Charles, Prince of Wales, Mariah Carey, Dame Shirley Bassey, Catherine Zeta-Jones and The Jacksons.