WIn physics, absorption of electromagnetic radiation is how matter takes up a photon's energy — and so transforms electromagnetic energy into internal energy of the absorber. A notable effect is attenuation, or the gradual reduction of the intensity of light waves as they propagate through a medium. Although the absorption of waves does not usually depend on their intensity, in certain conditions (optics) the medium's transparency changes by a factor that varies as a function of wave intensity, and saturable absorption occurs.
WAbsorption cross section is a measure for the probability of an absorption process. More generally, the term cross section is used in physics to quantify the probability of a certain particle-particle interaction, e.g., scattering, electromagnetic absorption, etc. In honor of the fundamental contribution of Maria Goeppert Mayer to this area, the unit for the two-photon absorption cross section is named the "GM". One GM is 10−50 cm4 s photon−1.
WAlbedo is the measure of the diffuse reflection of solar radiation out of the total solar radiation and measured on a scale from 0, corresponding to a black body that absorbs all incident radiation, to 1, corresponding to a body that reflects all incident radiation.
WAtmospheric optics is "the study of the optical characteristics of the atmosphere or products of atmospheric processes .... [including] temporal and spatial resolutions beyond those discernible with the naked eye". Meteorological optics is "that part of atmospheric optics concerned with the study of patterns observable with the naked eye". Nevertheless, the two terms are sometimes used interchangeably.
WIn physics, backscatter is the reflection of waves, particles, or signals back to the direction from which they came. It is usually a diffuse reflection due to scattering, as opposed to specular reflection as from a mirror, although specular backscattering can occur at normal incidence with a surface. Backscattering has important applications in astronomy, photography, and medical ultrasonography. The opposite effect is forward scatter, e.g. when a translucent material like a cloud diffuses sunlight, giving soft light.
WThe Beer–Lambert law, also known as Beer's law, the Lambert–Beer law, or the Beer–Lambert–Bouguer law relates the attenuation of light to the properties of the material through which the light is travelling. The law is commonly applied to chemical analysis measurements and used in understanding attenuation in physical optics, for photons, neutrons, or rarefied gases. In mathematical physics, this law arises as a solution of the BGK equation.
WIn atmospheric radiation, Chandrasekhar's H-function appears as the solutions of problems involving scattering, introduced by the Indian American astrophysicist Subrahmanyan Chandrasekhar. The Chandrasekhar's H-function defined in the interval , satisfies the following nonlinear integral equation
WIn physics, coherent backscattering is observed when coherent radiation propagates through a medium which has a large number of scattering centers of size comparable to the wavelength of the radiation.
WDiscrete dipole approximation (DDA), also known as coupled dipole approximation, is a method for computing scattering of radiation by particles of arbitrary shape and by periodic structures. Given a target of arbitrary geometry, one seeks to calculate its scattering and absorption properties by an approximation of the continuum target by a finite array of small polarizable dipoles. This technique is used in a variety of applications including nanophotonics, radar scattering, aerosol physics and astrophysics.
WDynamic light scattering (DLS) is a technique in physics that can be used to determine the size distribution profile of small particles in suspension or polymers in solution. In the scope of DLS, temporal fluctuations are usually analyzed by means of the intensity or photon auto-correlation function. In the time domain analysis, the autocorrelation function (ACF) usually decays starting from zero delay time, and faster dynamics due to smaller particles lead to faster decorrelation of scattered intensity trace. It has been shown that the intensity ACF is the Fourier transformation of the power spectrum, and therefore the DLS measurements can be equally well performed in the spectral domain. DLS can also be used to probe the behavior of complex fluids such as concentrated polymer solutions.
WElectrochromism is the phenomenon where the color or opacity of a material changes when a voltage is applied. By doing so, an electrochromic smart window can block ultraviolet, visible or (near) infrared light instantaneously and on demand. The ability to control transmittance of near infrared light can increase the energy efficiency of a building, reducing the amount of energy needed to cool during summer and heat during winter.
WFinite-difference time-domain (FDTD) or Yee's method is a numerical analysis technique used for modeling computational electrodynamics. Since it is a time-domain method, FDTD solutions can cover a wide frequency range with a single simulation run, and treat nonlinear material properties in a natural way.
WIn physics, telecommunications, and astronomy, forward scatter is the deflection—by diffraction, nonhomogeneous refraction, or nonspecular reflection by particulate matter of dimensions that are large with respect to the wavelength in question but small with respect to the beam diameter—of a portion of an incident electromagnetic wave, in such a manner that the energy so deflected propagates in a direction that is within 90° of the direction of propagation of the incident wave.
WA frequency-selective surface (FSS) is any thin, repetitive surface designed to reflect, transmit or absorb electromagnetic fields based on the frequency of the field. In this sense, an FSS is a type of optical filter or metal-mesh optical filters in which the filtering is accomplished by virtue of the regular, periodic pattern on the surface of the FSS. Though not explicitly mentioned in the name, FSS's also have properties which vary with incidence angle and polarization as well - these are unavoidable consequences of the way in which FSS's are constructed. Frequency-selective surfaces have been most commonly used in the radio frequency region of the electromagnetic spectrum and find use in applications as diverse as the aforementioned microwave oven, antenna radomes and modern metamaterials. Sometimes frequency selective surfaces are referred to simply as periodic surfaces and are a 2-dimensional analog of the new periodic volumes known as photonic crystals.
WA hail spike or three body scatter spike (TBSS) is an artifact on a weather radar display indicative of large hail. They are identified by a spike of weak reflectivity echoes that extend out from a thunderstorm, and away from the radar site.
WHyper–Rayleigh scattering Optical Activity, is a nonlinear optical physical effect whereby chiral scatterers convert light to higher frequencies via harmonic generation processes, in a way that the intensity of generated light depends on the chirality of the scatterers. "Hyper–Rayleigh scattering" is a nonlinear optical counterpart to Rayleigh scattering. "Optical activity" refers to any changes in light properties that are due to chirality.
WA localized surface plasmon (LSP) is the result of the confinement of a surface plasmon in a nanoparticle of size comparable to or smaller than the wavelength of light used to excite the plasmon. When a small spherical metallic nanoparticle is irradiated by light, the oscillating electric field causes the conduction electrons to oscillate coherently. When the electron cloud is displaced relative to its original position, a restoring force arises from Coulombic attraction between electrons and nuclei. This force causes the electron cloud to oscillate. The oscillation frequency is determined by the density of electrons, the effective electron mass, and the size and shape of the charge distribution. The LSP has two important effects: electric fields near the particle's surface are greatly enhanced and the particle's optical absorption has a maximum at the plasmon resonant frequency. Surface plasmon resonance can also be tuned based on the shape of the nanoparticle. The plasmon frequency can be related to the metal dielectric constant. The enhancement falls off quickly with distance from the surface and, for noble metal nanoparticles, the resonance occurs at visible wavelengths. Localized surface plasmon resonance creates brilliant colors in metal colloidal solutions.
WThe Mie solution to Maxwell's equations describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The solution takes the form of an infinite series of spherical multipole partial waves. It is named after Gustav Mie.
WThe near field and far field are regions of the electromagnetic field (EM) around an object, such as a transmitting antenna, or the result of radiation scattering off an object. Non-radiative near-field behaviors dominate close to the antenna or scattering object, while electromagnetic radiation far-field behaviors dominate at greater distances.
WOcean color is the branch of Ocean optics that specifically studies the color of the water and information that can be gained from looking at variations in color. The color of the ocean, while mainly blue, actually varies from blue to green or even yellow, brown or red in some cases. This field of study developed alongside water remote sensing, so it is focused mainly on how color is measured by instruments.
WOcean optics is the study of how light interacts with water and the materials in water. Although research often focuses on the sea, the field broadly includes rivers, lakes, inland waters, coastal waters, and large ocean basins. How light acts in water is critical to how ecosystems function underwater. Knowledge of ocean optics is needed in aquatic remote sensing research in order to understand what information can be extracted from the color of the water as it appears from satellite sensors in space. The color of the water as seen by satellites is known as ocean color. While ocean color is a key theme of ocean optics, optics is a broader term that also includes the development of underwater sensors using optical methods to study much more than just color, including ocean chemistry, particle size, imaging of microscopic plants and animals, and more.
WOpacity is the measure of impenetrability to electromagnetic or other kinds of radiation, especially visible light. In radiative transfer, it describes the absorption and scattering of radiation in a medium, such as a plasma, dielectric, shielding material, glass, etc. An opaque object is neither transparent nor translucent. When light strikes an interface between two substances, in general some may be reflected, some absorbed, some scattered, and the rest transmitted. Reflection can be diffuse, for example light reflecting off a white wall, or specular, for example light reflecting off a mirror. An opaque substance transmits no light, and therefore reflects, scatters, or absorbs all of it. Both mirrors and carbon black are opaque. Opacity depends on the frequency of the light being considered. For instance, some kinds of glass, while transparent in the visual range, are largely opaque to ultraviolet light. More extreme frequency-dependence is visible in the absorption lines of cold gases. Opacity can be quantified in many ways; for example, see the article mathematical descriptions of opacity.
WThe opposition surge is the brightening of a rough surface, or an object with many particles, when illuminated from directly behind the observer. The term is most widely used in astronomy, where generally it refers to the sudden noticeable increase in the brightness of a celestial body such as a planet, moon, or comet as its phase angle of observation approaches zero. It is so named because the reflected light from the Moon and Mars appear significantly brighter than predicted by simple Lambertian reflectance when at astronomical opposition. Two physical mechanisms have been proposed for this observational phenomenon: shadow hiding and coherent backscatter.
WIn physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to transmitted radiant power through a material. Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material. Spectral optical depth or spectral optical thickness is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material. Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of optical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged.
WPenetration depth is a measure of how deep light or any electromagnetic radiation can penetrate into a material. It is defined as the depth at which the intensity of the radiation inside the material falls to 1/e of its original value at the surface.
WPhase angle in astronomical observations is the angle between the light incident onto an observed object and the light reflected from the object. In the context of astronomical observations, this is usually the angle Sun-object-observer.
WPhoton transport in biological tissue can be equivalently modeled numerically with Monte Carlo simulations or analytically by the radiative transfer equation (RTE). However, the RTE is difficult to solve without introducing approximations. A common approximation summarized here is the diffusion approximation. Overall, solutions to the diffusion equation for photon transport are more computationally efficient, but less accurate than Monte Carlo simulations.
WRaman scattering or the Raman effect is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes Raman scattering. The effect is exploited by chemists and physicists to gain information about materials for a variety of purposes by performing various forms of Raman spectroscopy. Many other variants of Raman spectroscopy allow rotational energy to be examined and electronic energy levels may be examined if an X-ray source is used in addition to other possibilities. More complex techniques involving pulsed lasers, multiple laser beams and so on are known.
WRayleigh scattering, named after the nineteenth-century British physicist Lord Rayleigh, is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scattering particle, the amount of scattering is inversely proportional to the fourth power of the wavelength.
WScattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections of radiation that undergo scattering are often called diffuse reflections and unscattered reflections are called specular (mirror-like) reflections. Originally, the term was confined to light scattering. As more "ray"-like phenomena were discovered, the idea of scattering was extended to them, so that William Herschel could refer to the scattering of "heat rays" in 1800. John Tyndall, a pioneer in light scattering research, noted the connection between light scattering and acoustic scattering in the 1870s. Near the end of the 19th century, the scattering of cathode rays and X-rays was observed and discussed. With the discovery of subatomic particles and the development of quantum theory in the 20th century, the sense of the term became broader as it was recognized that the same mathematical frameworks used in light scattering could be applied to many other phenomena.
WSpectroscopy is the study of the interaction between matter and electromagnetic radiation as a function of the wavelength or frequency of the radiation. In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum; indeed, historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).
WA split-ring resonator (SRR) is an artificially produced structure common to metamaterials. Their purpose is to produce the desired magnetic susceptibility in various types of metamaterials up to 200 terahertz. These media create the necessary strong magnetic coupling to an applied electromagnetic field, not otherwise available in conventional materials. For example, an effect such as negative permeability is produced with a periodic array of split ring resonators.
WSubsurface scattering (SSS), also known as subsurface light transport (SSLT), is a mechanism of light transport in which light that penetrates the surface of a translucent object is scattered by interacting with the material and exits the surface at a different point. The light will generally penetrate the surface and be reflected a number of times at irregular angles inside the material before passing back out of the material at a different angle than it would have had if it had been reflected directly off the surface. Subsurface scattering is important for realistic 3D computer graphics, being necessary for the rendering of materials such as marble, skin, leaves, wax and milk. If subsurface scattering is not implemented, the material may look unnatural, like plastic or metal.
WThe transport length in a strongly diffusing medium is the length over which the direction of propagation of the photon is randomized. It is related to the mean free path l by the relation:
WThe Tyndall effect is light scattering by particles in a colloid or in a very fine suspension. Also known as Tyndall scattering, it is similar to Rayleigh scattering, in that the intensity of the scattered light is inversely proportional to the fourth power of the wavelength, so blue light is scattered much more strongly than red light. An example in everyday life is the blue colour sometimes seen in the smoke emitted by motorcycles, in particular two-stroke machines where the burnt engine oil provides these particles.
WThe Umkehr is the time variation of the ratio of the scattered intensity at two different wavelengths. The word means 'reversal' in German. The Umkehr effect is observed when measurements are made with ultraviolet spectrophotometer of the ratio of the zenith sky light intensities of two wavelengths in the solar ultraviolet when the sun is near the horizon. The shorter of two wavelengths (intensity I) is strongly absorbed and other (intensity I' ) is weakly absorbed. If the value of log(I/I' ) is plotted against the sun's zenith angle, it is observed that this log-intensity ratio decreases as the zenith angle increases until a minimum is reached for a zenith angle of about 80 (when the wavelengths are 3114 and 3324 A0). This effect was first noticed by Götz in 1930. The Umkehr measurement is known as customarily N-value and is given by the logarithm base 10 of the ratio of cloudless zenith sky intensities at two different wavelengths scaled by a multiplicative factor 100 plus a constant which depends on instruments and extraterrestrial radiation. Methods for deriving vertical distribution from the umkehr measurements were developed by Götz, Dobson and Meetham in 1934, using the Dobson ozone spectrophotometer developed by Gordon Dobson. In 1964 Carlton Mateer provided analysis on information content in umkehr measurements.
WThe zero-phonon line and the phonon sideband jointly constitute the line shape of individual light absorbing and emitting molecules (chromophores) embedded into a transparent solid matrix. When the host matrix contains many chromophores, each will contribute a zero-phonon line and a phonon sideband to the absorption and emission spectra. The spectra originating from a collection of identical chromophores in a matrix is said to be inhomogeneously broadened because each chromophore is surrounded by a somewhat different matrix environment which modifies the energy required for an electronic transition. In an inhomogeneous distribution of chromophores, individual zero-phonon line and phonon sideband positions are therefore shifted and overlapping.