
Carlo Balabio (1759–1838) was an Italian general and cavalry commander who served the Kingdom of Italy during the Napoleonic Wars.

Antonio Bertoletti, also known as Antoine Marc Augustin Bertoletti was a Milanese military officer who served the French Empire as a general of brigade, notably in the Peninsular War.

Don Camillo Filippo Ludovico Borghese, Prince of Sulmona and of Rossano, Duke and Prince of Guastalla was a member of the Borghese family, best known for being a brother-in-law of Napoleon.

Prince Francesco Caracciolo was an Italian admiral and revolutionary.

Giovanni Battista Agostino Codazzi was an Italo-Venezuelan soldier, scientist, geographer, cartographer, and governor of Barinas (1846-1847). He made his main investigations and cartographic work in Venezuela and Colombia, thereby creating for both countries a complete set of maps and statistics after the tumultuous years following independence from the Spanish Empire.

Giorgio des Geneys was an Italian admiral.

Achille Fontanelli was an Italian nationalist and Napoleonic general. Born into a low-ranking noble family, he took service with a pro-French Italian military unit in 1797. He was captured in 1799 but was repatriated in time to serve in the Marengo Campaign in 1800. He was promoted to general officer in 1804 and in the 1809 war he led an Italian division in several major battles. After serving as Minister of War to Eugène de Beauharnais, he was tapped to command a division in the 1813 campaign. After the collapse of Napoleon's empire in 1814, he took service with the Austrian Empire.

Pompeo Gabrielli was an Italian general and politician, the first layman to be appointed Minister in a Papal States cabinet.

Giuseppe ("Joseph") Lechi was an Italian general in the Kingdom of Italy during the Napoleonic Wars.

Teodoro Lechi was an Italian general, a Jacobin and a military advisor to King Carlo Alberto of Sardinia. He was the brother of Giuseppe Lechi, a brilliant and famous Napoleonic general, and Angelo, also a Napoleonic officer.

Count Pompeo Litta Biumi or Pompeo Litta was an Italian historian, genealogist, military officer, politician, and nobleman.

Colonel Francis Maceroni, born Francis Macirone (1788–1846), was a soldier, diplomat, revolutionary, balloonist, author and inventor.

Alberto Ferrero La Marmora was an Italian soldier and naturalist. He was elder brother to Alessandro Ferrero La Marmora, soldier and founder of the Bersaglieri, and to Alfonso Ferrero La Marmora, Italian general and statesman.

Domenico Millelire, pseudonym of Domenico Leoni, was an Italian patriot, and officer of Regia Marina Sarda. He is recognised to have gained the first Gold Medal of Military Valor in the Italian history. Millelire gave the first defeat to Napoleon Bonaparte.

Giuseppe Federico Palombini or Joseph Friedrich von Palombini became an Italian division commander during the Napoleonic Wars. He joined the army of the Cispadane Republic in 1796 and fought at Faenza in 1797. He became commander of a dragoon regiment in 1798. He became commander of the Napoleone Dragoons, of the Cisalpine Republic army, in 1802. He fought as an ally of the French at Kolberg and Stralsund in 1807. He married the daughter of Jan Henryk Dąbrowski (Dombrowski) in 1806.

Filippo Paulucci delle Roncole, also known as Filipp Osipovich Pauluchchi, was an Italian marquis and army officer, later a general at the services of the Kingdom of Sardinia, the Holy Roman Empire, the Kingdom of Italy, and the Russian Empire.

Guglielmo Pepe was an Italian general and patriot. He was brother to Florestano Pepe and cousin to Gabriele Pepe. He was married to Mary Ann Coventry, a Scottish woman who was the widow of John Borthwick Gilchrist, linguist and surgeon to the East India Company.

Ettore Perrone, Conte di San Martino was an Italian politician and military leader.

Domenico ("Dominique") Pino was an Italian soldier. He served as General of Division in the Kingdom of Italy and in Napoleon's Grande Armée.

General Girolamo Ramorino was born in Genoa, in northern Italy.

Giuseppe Rondizzoni was an Italian army officer who contributed to the independence of Chile.
Santorre Annibale De Rossi di Pomerolo, Count of Santa Rosa was an Italian insurgent and leader in Italy's revival (Risorgimento).

Filippo Severoli was an Italian general and noble who served in the Kingdom of Italy during the Napoleonic Wars and in the Austrian Empire. He was named Earl of Hannover and governor of Piacenza by Napoleon Bonaparte.

Pietro Teulié was an Italian general who served in the Kingdom of Italy during the Napoleonic Wars. He was killed during the siege of the Prussian fortress of Kolberg.

Carlo Zucchi, was an Italian general and patriot, who served in the Kingdom of Italy and later in the Papal State. He played an active role in the Risorgimento. His namesake nephew was a notable architect.