
André Antoine is a Belgian politician, minister and mayor. He has been a member of the francophone cdH since 1980. He was elected to the presidency of the Wallon parliament on 22 July 2014.

Wouter Beke is a Belgian politician and a member of the CD&V. He was reelected as a member of the Belgian Senate in 2007. In 2014 he became a member of the Belgian Federal House of Representatives and was reelected in 2019. In July 2019 he succeeded Kris Peeters as Federal Minister for Work, Economy and Consumer affairs. He left the Belgian Federal Government in October 2019 to become Minister for Welfare, Public health, Family and Poverty reduction in the Flemish Regional Jambon Government.

François Bellot is a Belgian politician. He is a member of the Reformist Movement (MR) party. He served as the Federal Minister for Mobility and Transport in the Wilmès' caretaker Government from April 17, 2016 to October 1, 2020.

Jonkheer Henri Ghislain Joseph Marie Hyacinthe de Brouckère was a Belgian nobleman and liberal politician. Born in Bruges, he was a magistrate, and a professor at the Université Libre de Bruxelles. His brother Charles was mayor of Brussels.

Idès Cauchie is a Belgian politician (cdH). On 5 February 2014 he became a member of the Parliament of Wallonia following the death of Damien Yzerbyt.
Bernard Clerfayt is a Belgian politician. He has been the mayor of Schaerbeek since 2001 and is currently vice-president of the Front Démocratique des Francophones (FDF). As is common in Belgium, he holds a dual mandate and has also been a member of the federal Belgian Chamber of Representatives since 2007.

Léo Collard was a Belgian politician in the Belgian Socialist Party (PSB–BSP) who served as minister of public education and Mayor of Mons (1953–1974).

Armand De Decker was a Belgian politician and member of the French-speaking liberal party Mouvement Réformateur (MR).

Louis Defré (1816-1880), was a burgomaster mayor of Uccle, Belgium, from 1864 to 1872, and deputy

Rudy W.G. Demotte is a Belgian socialist politician who served as 12th Minister-President of Wallonia (2007–2014), replacing Elio Di Rupo, one month after a historical defeat of the socialists in the federal election.

Jean-Pierre Detremmerie was a Belgian politician and long serving former mayor of Mouscron. He was active within the francophone Christian Democratic Party (cdH) for many years, and a Member of Parliament between 1981 and 2003.

Elio Di Rupo is a Belgian socialist politician who is the Minister-President of Wallonia. He served as the Prime Minister of Belgium from 6 December 2011 to 11 October 2014, and headed the Di Rupo Government. Di Rupo was the first francophone to hold the office since Paul Vanden Boeynants in 1979, and the country's first socialist Prime Minister since Edmond Leburton left office in 1974. He was also Belgium's first Prime Minister of non-Belgian descent, and the world's second openly gay person and first openly gay man to be head of government in modern times.

Charles Joseph Marie, 6th Duke d'Ursel, was a Belgian politician.

Robert-Marie-Léon 7th Duke d'Ursel (1873–1955) was a Belgian politician.

Theo Francken is a Belgian politician who has been a member of the Chamber of Representatives since 2010. He is a member of the New Flemish Alliance (N-VA), a conservative Flemish nationalist party.

Paul Furlan is a Walloon politician and former Minister of Local Government and City Policy in the Walloon Government for the Parti Socialiste. Furlan has a degree in public administration obtained at the University of Liège.

Alfred Gadenne was a Belgian politician for the Centre démocrate humaniste and mayor of Mouscron in Hainaut until his death in September 2017.

Jean, Count Goblet d'Alviella, was the mayor of Court-Saint-Étienne. He was married with June Corfield. Together they have four children: Richard Goblet d'Alviella, Christine Goblet d'Alviella, Patrick Goblet d'Alviella, and Michael Goblet d'Alviella. He is a son of Félix Goblet d'Alviella.

Count Michael Goblet d'Alviella is a Belgian liberal politician, counsel-general, and mayor of Court-Saint-Étienne. He is a son of Jean Goblet d'Alviella and his wife, June Dierdre Corfield. He is the grandson of Sir Conrad Laurence Corfield.

Paul-François Huart-Chapel (1770–1850), was a Belgian industrialist, and politician.

Leopold Raymond Maurice François Marie Ghislain Lippens was a Belgian politician. He was mayor of Knokke-Heist for over 40 years, between 1979 until his death in 2021. The football stadium Burgemeester Graaf Leopold Lippens Park is named after him after the renovation in 2019. He was accused in the X-Dossier files as being a child abuser.
Maurice Auguste Count Lippens was a noble Belgian businessman, politician, and colonial civil servant and lawyer.

Anne-Marie Lizin-Vanderspeeten was a Belgian politician, who served as the President of the Senate of Belgium from 2004 to 2007.

Benoît Lutgen is a Belgian politician who served as head of the Centre démocrate humaniste political party in Belgium from 2011 to 2019.

Joseph Michel was a Christian-Democrat Belgian politician, member of the PSC, who was President of the Belgian Chamber of Representatives (1980–81) and who twice served as Minister of the Interior.

Philippe Moureaux was a Belgian politician, senator, mayor of Molenbeek-Saint-Jean, and professor of economic history at the Université Libre de Bruxelles. He held the honorary title of Minister of State and was a member of the Order of Leopold II and the Order of Leopold.

Jacques Louis Gustave Van Offelen was a Belgian liberal politician, burgomaster and minister for the PVV. He graduated from the Institut Supérieur de Commerce de l'Etat (1938) in Antwerp, and in 1939 became a licentiate in economy at the Universite Libre de Bruxelles. He obtained a PhD from the University of Liège in 1943 and became a civil servant and docent.

Vincent Van Peteghem is a Belgian economist and politician of CD&V who has been serving as Minister of Finance in the government of Prime Minister Alexander De Croo since 1 October 2020. He was a member of the Chamber of Representatives of Belgium from 2014 until 2020.

Charles Picqué is a Belgian politician. He is a former Minister-President of the Brussels Capital-Region.

Etienne Adolf Schouppe is a Belgian politician. He is a member of the Christen-Democratisch en Vlaams party. Before his entry into politics, he was executive manager of the National Railway Company of Belgium. Schouppe was a member of the Belgian Senate from 2003 to 2010 and since 2008 the State Secretary for Mobility. At the local level Schouppe was mayor of Liedekerke for eleven years. In 2010 he retired from politics. In 2010 he was also accused of insider trading for having sold KBC and Dexia shares with special information.

Steve Stevaert was a Belgian politician of the Flemish Socialist Party: the SP.A.

Leonard Clemence "Leo" Tindemans was a Belgian politician. He served as the Prime Minister of Belgium serving from 25 April 1974 until he resigned as minister on 20 October 1978. He was a member of the Christian Democratic and Flemish party.

Louis Marie Joseph Tobback is a Belgian politician. Tobback is a Flemish social democrat and member of the political party SP.A. He was the mayor of Leuven (1995–2018) He graduated in Roman philology at the Vrije Universiteit Brussel. He is the father of Bruno Tobback, the former president of the Flemish socialist party Different Socialist Party (SP.A).

Steven Vandeput is a Belgian politician and is affiliated to the N-VA. He was elected as a member of the Belgian Chamber of Representatives in 2010.

Peter Karel Alexander Vanvelthoven is a Belgian politician and member of the SP.A. He is the son of politician Louis Vanvelthoven. He became the Federal Minister for Employment, charged with the Informatisation of the State, in 2005 after Deputy Prime Minister and Minister of Budget Johan Vande Lanotte left the Federal Government to become the President of the Different Socialist Party (SP.A).

Jan Verroken was a Belgian politician.

Rudi Vervoort is a Brussels politician. He is the mayor of Evere since 1998 and member of the Brussels Parliament. He became the Minister-President of the Brussels-Capital Region on 7 May 2013 and is responsible for Local Authorities, Urban Development, Monuments and Sites, Environmental Maintenance, Development Cooperation and Regional Statistics.

Viscount Charles Ghislain Guillaume Vilain XIIII was a Belgian politician, serving as governor of East Flanders, Minister of Foreign Affairs and President of the Chamber of Representatives of Belgium.

Frederik A. A. Willockx is a Belgian socialist politician, member of the Flemish Different Socialist Party.