
Ivan Fedorovych Drach was a Ukrainian poet, screenwriter, literary critic, politician, and political activist.

Ivan Dziuba is a Ukrainian literary critic, social activist, Russian philologist, dissident, Hero of Ukraine, academic of National Academy of Sciences of Ukraine, the second Minister of Culture of Ukraine (1992—1994), Head of the Committee for Shevchenko National Prize (1999–2001).

Marko Farion is a Ukrainian bandurist, opera singer and dentist. Farion currently resides in Sterling Heights, Michigan.

Patriarch Filaret is the primate and Patriarch of the Ukrainian Orthodox Church – Kyiv Patriarchate. He was the honorary Patriarch of the Orthodox Church of Ukraine (2018–2019), and the former Metropolitan of Kyiv of the Russian Orthodox Church (1966–1992). He was defrocked and in 1997 excommunicated by the ROC.

Georgiy Ruslanovich Gongadze was a Ukrainian journalist and film director who was kidnapped and murdered in 2000 near Kyiv. He founded the internet newspaper Ukrayinska Pravda along with Olena Prytula in 2000.

Oleksandr Vasylyovych Halunenko is a Ukrainian test pilot, Honoured Test Pilot of the USSR, the president of the Ukrainian Federation of Aeronautical Sports, and recipient of the title Hero of Ukraine.

Vadym Petrovych Hetman was a Ukrainian statesman and banker. He is credited with the creation of the central bank of the country, the National Bank of Ukraine.

Oleksa Mykolajovych Hirnyk was a Ukrainian Soviet dissident, an engineer by profession, who burned himself to death as an act of protest against Soviet suppression of the Ukrainian language (russification), culture and history. The act was quickly covered up by the Soviet authorities and remained unknown to general populace for decades. He was convicted in treason by Polish Republic and then the Soviet Union.

Dmytro Hnatyuk was a Soviet and Ukrainian baritone opera singer and a former member of the Ukrainian Parliament.

Oleksandr "Oles" Terentiyovych Honchar was a Soviet and Ukrainian writer and public figure. He also was a veteran of World War II and member of the Ukrainian parliament.
Olena Yuriyivna Iurkovska is a cross-country skier and biathlete from Ukraine, and a five time Paralympic Champion. She has competed at every Winter Paralympic Games since 2002, winning a total of five gold, five silver, and five bronze medals up to 2010. She also competed at the 2004 Summer Paralympics, as a member of the Ukrainian volleyball team.

Roman Ivanovych Ivanychuk was a Ukrainian writer and politician. He was the 1985 laureate of the Shevchenko National Prize. Between 1990 and 1994 he was a deputy of the Verkhovna Rada. In 2009, he received a title of Hero of Ukraine.

Volodymyr Mykhailovych Ivasyuk or Volodymyr Ivasiuk was a Ukrainian songwriter, composer and poet. He is the author and composer of the widely popular song "Chervona Ruta" popularized by Sofia Rotaru in 1971, and later covered by other singers.

Leonid Kostyantynovych Kadenyuk was the first astronaut of independent Ukraine who flew into outer space. He flew on NASA's Space Shuttle Columbia in 1997 as part of the international mission STS-87. Kadenyuk held the rank of Major general in the Ukrainian Air Force. He was Deputy of Ukraine of the 4th convocation, People's Ambassador of Ukraine, Hero of Ukraine, President of the Aerospace Society of Ukraine, Adviser to the Prime Minister of Ukraine and Chairman of the State Space Agency of Ukraine, Honorary Doctor of Chernivtsi National University.

Heorhiy Mykolayovych Kirpa was a Ukrainian railway manager, statesman and politician, best known as the head of the Ukrzaliznytsia national railway company and Minister of Transportation and Telecommunications under President Leonid Kuchma.

Vitali Volodymyrovych Klitschko is a Ukrainian politician and former professional boxer. He currently serves as Mayor of Kyiv and head of the Kyiv City State Administration, having held both offices since June 2014. Klitschko is a former leader of the Petro Poroshenko Bloc and a former Member of the Ukrainian Parliament. He became actively involved in Ukrainian politics in 2005 and combined this with his professional boxing career until his retirement from the sport in 2013.

Yana Oleksandrivna Klochkova is a Ukrainian swimmer, who has won five Olympic medals in her career, with four of them being gold. She is Merited Master of Sports (1998), Hero of Ukraine (2004) and the most awarded Olympian from Ukraine.

Mykola Filaretovich Kolessa was a Ukrainian composer and conductor, born in Sambir near Lviv.

Yuriy Kosiuk is a Ukrainian billionaire, and CEO of the country's largest agricultural company MHP, and chairman of PJSC Myronivsky Hliboproduct.

Ihor Ihorovych Kostenko was a Ukrainian journalist, student activist and Wikipedian killed during the Euromaidan events.
Leonid Makarovych Kravchuk is a former Ukrainian politician and the first President of Ukraine, who served from 5 December 1991 until 19 July 1994. He is also a former Chairman of the Verkhovna Rada and People's Deputy of Ukraine serving in the Social Democratic Party of Ukraine (united) faction.

Maksym Serhiyovich Krypak is a Paralympic swimmer from Ukraine who competes in S10 and SM10 events. He won five gold and three silver medals at the 2016 Rio Paralympics, setting new world records in the 100 m backstroke and 400 m freestyle.

Hryhoriy Trokhymovych Kytasty was a Ukrainian émigré composer and conductor. In 2008 he was honored with the Hero of Ukraine state decoration.

Valeriy Vasylyovych Lobanovskyi was а Ukrainian football player and manager. He was Master of Sports of the USSR, Distinguished Coach of the USSR, and a laureate of the UEFA Order of Merit in Ruby (2002) and FIFA Order of Merit, the highest honour awarded by FIFA. In 2002 he was awarded the Hero of Ukraine award (posthumously), the highest Ukrainian honour, for his contribution to Ukrainian football. In 2008, Lobanovskyi was ranked 6th in Inter's list of the 100 Greatest Ukrainians following a nation-wide poll that saw around 2.5 million people casting their votes.

Levko Hryhorovych Lukianenko was a Ukrainian politician, and Soviet dissident and Hero of Ukraine. He was one of the founders of Ukrainian Helsinki Group in 1976 and was elected a leader of the revived Ukrainian Helsinki Group, Ukrainian Helsinki Association, in 1988.

Volodymyr Mykhailovych Lytvyn is a Ukrainian politician best known for being Chairman of the Verkhovna Rada, the Ukrainian parliament. Having previously served in that position from 2002 until 2006, he was re-elected in December 2008 after his party agreed to join the former coalition of Yulia Tymoshenko in an expanded capacity and stayed Chairman till December 2012. From 1994 to 1999, Lytvyn was the aide to President Leonid Kuchma and, later, the head of his office.

Tetyana Yosypivna Markus was a member of the anti-Nazi underground in Kiev.

Nina Mytrofanivna Matviyenko, a Ukrainian singer, People's Artist of Ukraine.
Serhiy Gagikovych Nigoyan or Nihoyan was an Armenian-Ukrainian Euromaidan activist who was fatally shot during the 2014 Hrushevskoho Street riots where he was acting as security. He was the first protester killed by shooting during the protest.

Borys Illich Oliynyk was a Ukrainian poet, translator, and political activist. He served in the Verkhovna Rada from 1992 to 2006 and was chairman of the Ukrainian Culture Fund.

Oleksandr Oleksandrovych Omelchenko became the mayor of Kyiv, the capital of Ukraine, in 1999. He lost his re-election bid in March 2006. Omelchenko is also a former member of the Verkhovna Rada.

Borys Yevhenovych Paton HOU was a Soviet and Ukrainian scientist and a long-time chairman of the National Academy of Sciences of Ukraine. He was appointed to this post in 1962 and held it until his death. Paton, like his father Evgeny Paton, was famous for his works in electric welding.

Dmytro Pavlychko is a Ukrainian poet, translator, scriptwriter, culturologist, political and public figure.

Ivan Stepanovych Plyushch was a Ukrainian politician. He thrice served as the Chairman of the Verkhovna Rada, from July 9 to July 23, 1990 (acting), from December 5, 1991, to May 11, 1994, and from February 1, 2000, to May 14, 2002.

Sofiia Mykhailivna Yevdokymenko-Rotaru, known as Sofia Rotaru, is a former Soviet and Ukrainian pop singer of Romanian origin.

Mykola Danylovych Rudenko was a Ukrainian poet, writer, philosopher, Soviet dissident, human rights activist and World War II veteran. He was the founder of the Ukrainian Helsinki group, and was twice arrested for his dissident activities.

Metropolitan Vladimir was the head of the Ukrainian Orthodox Church (UOC-MP) from 1992 to 2014. Metropolitan Volodymyr's official title was His Beatitude Vladimir, Metropolitan of Kyiv and all Ukraine. As head of the Ukrainian Orthodox Church, he was the head of the only Ukrainian Church inside Ukraine to have canonical standing in Eastern Orthodoxy worldwide.

Nadiya Viktorivna Savchenko is a Ukrainian politician and former Army aviation pilot in the Ukrainian Ground Forces, and former People's Deputy of Ukraine.

Anatoly Pavlovich Shapiro, was a Ukrainian-born Jewish soldier of the Army of the Soviet Union, who led the first elements of the advancing army into the Nazi-developed Auschwitz concentration camp in Poland, during the latter stages of World War II. He was awarded: two Orders of the Red Star; two Orders of the Patriotic War of the 1st degree, for the Liberation of Kraków; the Order of the Patriotic War of the 2nd degree, and numerous other medals.

Maksym Shapoval was a senior officer (Colonel) in the Ukrainian military and head of the special forces of the Chief Intelligence Directorate. Col. Shapoval had only recently returned from the conflict zone in eastern Ukraine, and on 27 June 2017, he was assassinated in a car bomb attack in central Kyiv. At the time of his death, Shapoval was investigating Russian involvement in Eastern Ukraine. He collected intel on their locations and weapons, which was able to substantiate Ukraine's position in the war criminal trial in The Hague on Russia's armed aggression. At the time, he was one of the most senior Ukrainian officials killed in action.

Andriy Mykolayovych Shevchenko is a Ukrainian football manager who was most recently the manager of the Ukraine national team. He is also a former professional football player and a former politician. Shevchenko played as a striker for Dynamo Kyiv, AC Milan, Chelsea and the Ukraine national team. From February to July 2016, Shevchenko was an assistant coach of the Ukraine national team, at the time led by Mykhaylo Fomenko. In July 2016, shortly after the nation's elimination from UEFA Euro 2016, Shevchenko was appointed Ukraine's head coach.

Yuriy-Bohdan Romanovych Shukhevych is a Ukrainian politician, member of the Ukrainian Helsinki Group, political prisoner, son of Roman Shukhevych. He is a former long serving leader of the Ukrainian National Assembly – Ukrainian National Self Defence. Shukhevych spent over 30 years in the Soviet prisons and concentration camps. In the 2014 Ukrainian parliamentary election Shukhevych was elected into the Ukrainian parliament for Radical Party.
Myroslav Skoryk was a Ukrainian composer and teacher. His music is contemporary in style and contains idioms from diverse sources including German, Welsh, English, and Eastern European artistic traditions.

Anatoliy Solovianenko was a Ukrainian operatic tenor, People's Artist of the USSR (1975), People's Artist of Ukraine, and State Taras Shevchenko prize-winner.

Volodymyr Stelmakh — banker, economist, politician and Governor of the National Bank of Ukraine from January 21, 2000 – December 17, 2002 and December 16, 2004 – December 23, 2010.

Bohdan Sylvestrovych Stupka was a popular Ukrainian actor and the minister of culture of Ukraine. He was born in Kulykiv, General Government to Ukrainian parents. In 2001 he was a member of the jury at the 23rd Moscow International Film Festival. At the 26th Moscow International Film Festival he won the award for Best Actor for his role in Our Own.

Vasyl Semenovych Stus was a Ukrainian poet, translator, literary critic, journalist, and an active member of the Ukrainian dissident movement. For his political convictions, his works were banned by the Soviet regime and he spent 13 years in detention, until his death in Perm-36—then a Soviet forced labor camp for political prisoners, subsequently The Museum of the History of Political Repression—after having declared a hunger strike on September 4, 1985. On November 26, 2005, the Ukrainian president Viktor Yushchenko posthumously awarded him the highest national title: Hero of Ukraine. Stus is widely regarded as one of Ukraine's foremost poets.

Valeriy Sushkevych is a Ukrainian politician and public figure. Member of Verhovna Rada. President of the National Committee of Sports for the Disabled of Ukraine, head of the Ukrainian public socio-political association "National Assembly of Disabled of Ukraine", president of the Association "Sports Industry of Ukraine."

Valentyn Kostyantynovych Symonenko is a Ukrainian politician and former Soviet Communist Party functionary. Between 1996 and 2011 he was chairman of the Accounting Chamber of Ukraine.

Petro Tronko was a Ukrainian academician of the National Academy of Sciences of Ukraine and veteran of World War II.

Ivan Vakarchuk was a Ukrainian and Soviet physicist, politician and social activist. From 1990 to 2007 and again between 2010 and 2013 he was Rector of the Lviv University. In 2007–2010 he was Minister of Education and Science of Ukraine. Hero of Ukraine, he was father of the leader of the rock band Okean Elzy Svyatoslav Vakarchuk.

Vasylʹ Maxymovych Moroz is a Ukrainian academic.

Rev. Avgustyn Ivanovych Voloshyn was a Carpatho-Ukrainian politician, teacher, essayist, priest of the Mukacheve eparchy in Czechoslovakia of the Greek Catholic Church. He was president of the independent Carpatho-Ukraine, which existed for one day on March 15, 1939.

Tetyana Nilivna Yablonska was a Ukrainian painter. Her early vital pictures are devoted to work and a life of Ukrainian people. She has passed to generalizing images of the nature, differing a subtlety of plastic and color rhythms.
Ihor Yukhnovskyi is a Ukrainian physicist and politician, and a member of the Presidium of Academy of Sciences of Ukraine, Hero of Ukraine.

Mykhailo Vitaliyovych Zabrodskyi is since the 2019 Ukrainian parliamentary election a member of the Ukrainian parliament for the party European Solidarity.

Pavlo Arhypovych Zahrebelnyi or Zagrebelnyi was a Ukrainian novelist.

Valeriya Gavriilovna Zaklunna-Myronenko was a Soviet and Ukrainian actress and politician. A member of the Communist Party of Ukraine, she was a co-winner, with other members of the cast of the film To The Last Minute, of the 1975 Shevchenko National Prize.

Vasyl Ivanovich Zubanych is a colonel in the Ukrainian Ground Forces and a Hero of Ukraine. Zubanych was awarded the title Hero of Ukraine for his leadership of 15th Separate Mountain Battalion of the 128th Mountain Brigade in the fighting for Luhansk International Airport and the Battle of Debaltseve. In late 2015, he became the commander of the 10th Mountain Brigade.

Yukhym Leonidovych Zvyahilsky is a Ukrainian politician. He is the only member of Verkhovna Rada who was elected to parliament in eight elections.