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The Permanent Representative to the North Atlantic Council is the senior member of the United Kingdom's delegation to the North Atlantic Treaty Organization.

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Sir Emyr Jones Parry is a Welsh retired diplomat. He is a former Permanent Representative of the United Kingdom to the United Nations and former UK Permanent Representative on the North Atlantic Council.

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Dame Alison Mariot Leslie,, known as Mariot Leslie, is a former British diplomat whose last post was Permanent Representative to NATO. When she was replaced at NATO it was announced that she would retire from the Diplomatic Service.

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Dame Sarah MacIntosh is a British diplomat who is the British Ambassador to NATO. She previously served as High Commissioner to Sierra Leone and Ambassador to Liberia from 2006 to 2008.

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Sir David Geoffrey Manning, is a former British diplomat, who was the British Ambassador to the United States from 2003 to 2007. He authored the so-called "Manning Memo", that summarized the details of a meeting between American president George W. Bush and British prime minister Tony Blair during the run-up to the invasion of Iraq in 2003. Until 2019, he was appointed to the Household of TRH the Duke and Duchess of Cambridge and the Duke and Duchess of Sussex.

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Peter Forbes Ricketts, Baron Ricketts, is a retired British senior diplomat and a life peer. He has sat as a crossbencher in the House of Lords since 2016.

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Sir Adam McClure Thomson is a former British diplomat who is director of the European Leadership Network, a pan-European think tank based in London. He served as Permanent Representative to NATO between 2014 and 2016.