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Lieutenant General Sir George Tom Molesworth Bridges known as Sir Tom Bridges, was a British military officer and the 19th Governor of South Australia.

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Lieutenant General Sir Charles James Briggs, was a British Army officer who held high command in World War I.

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Lieutenant-General Sir Adrian Paul Ghislain Carton de Wiart, was a British Army officer born of Belgian and Irish parents. He was awarded the Victoria Cross, the highest military decoration awarded for valour "in the face of the enemy" in various Commonwealth countries. He served in the Boer War, First World War, and Second World War. He was shot in the face, head, stomach, ankle, leg, hip, and ear; was blinded in his left eye; survived two plane crashes; tunnelled out of a prisoner-of-war camp; and tore off his own fingers when a doctor declined to amputate them. Describing his experiences in the First World War, he wrote, "Frankly I had enjoyed the war."

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Major Dr. Thomas Joseph Crean, was an Irish rugby union player, British Army soldier and doctor. During the Second Boer War, while serving with the Imperial Light Horse, he was awarded the Victoria Cross. In 1902, he was made an Honorary Fellow of the Royal College of Surgeons. During the First World War he served with the Royal Army Medical Corps and was awarded the Distinguished Service Order.

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George Aubrey Faulkner was a South African cricketer who played 25 Test matches for South Africa and fought in both the Second Boer War and World War I. In cricket, he was an all-rounder who was among the best batsmen in the world at his peak and was one of the first leg spin bowlers to use the googly.

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Grantley Thomas Smart Goulding was a British athlete. He competed at the 1896 Summer Olympics in Athens.

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Major Robert Johnston, VC, was an Irish rugby union player and soldier. During the Second Boer War, Johnston was awarded the Victoria Cross while serving with the Imperial Light Horse. He played rugby for both Ireland and the British Lions. He is one of three Ireland rugby union internationals to have been awarded the Victoria Cross. The other two are Thomas Crean, who also served with the Imperial Light Horse in the Second Boer War, and Frederick Harvey who served in the First World War. Johnston, Crean and Harvey all played club rugby for Wanderers. In 1896 Johnston and Crean were also members of the same British Lions squad that toured South Africa . Johnston was also one of three alumni of King William's College to have been awarded the VC. The other two were George Stuart White and Robert Henry Cain. White served in the Second Anglo-Afghan War and Cain served in the Second World War.

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Major Charles Herbert Mullins VC CMG was a South African recipient of the Victoria Cross, the highest and most prestigious award for gallantry in the face of the enemy that can be awarded to British and Commonwealth forces.