
The National Transitional Council of Libya, sometimes known as the Transitional National Council, was the de facto government of Libya for a period during and after the Libyan Civil War, in which rebel forces overthrew the Libyan Arab Jamahiriya of Muammar Gaddafi. The NTC governed Libya for a period of ten months after the end of the war, holding elections to a General National Congress on 7 July 2012, and handing power to the newly elected assembly on 8 August.

Mustafa Abdul Jalil is a Libyan politician who was the Chairman of the National Transitional Council from 5 March 2011 until its dissolution on 8 August 2012. This position meant he was de facto head of state during a transitional period after the fall of Muammar Gaddafi's government in the Libyan Civil War, and until the handover of power to the General National Congress.

Dr. Naeem M. Abdurrahman P.h.D, PE is a Libyan nuclear scientist, engineer and academic. He was named Libya's Minister of Higher Education and Scientific Research on 22 November 2011 by Prime Minister Abdurrahim El-Keib.
Mustafa A.G. Abushagur is a Libyan politician, professor of electrical engineering, university president and entrepreneur. He served as interim Deputy Prime Minister of Libya from 22 November 2011 to 14 November 2012 in Abdurrahim El-Keib's cabinet and was briefly elected to succeed El-Keib as Prime Minister in 2012, before failing to receive congressional approval for his cabinet nominees and being removed from office.

Ashour Ben Khayal, sometimes romanised Ben Hayal, is a Libyan diplomat and politician who was born in the Cyrenaican city of Derna in September 1939. He was named Foreign Minister on 22 November 2011 by Abdurrahim El-Keib in a surprise move, as the position was originally reported to be filled by Libya's deputy ambassador to United Nations Ibrahim Dabbashi. He was described as little-known prior to his appointment.

Salwa Bugaighis was a Libyan human rights and political activist. She was assassinated in Benghazi, Libya on June 25, 2014.

Salwa Fawzi El-Deghali is a Libyan academic and a member of the National Transitional Council representing women and in charge of legal affairs. El-Deghali possess a Doctor of Philosophy in constitutional law. She taught at the Academy of Graduate Studies in Benghazi.
Anwar Elfeitori is a Libyan Telecommunications Engineer born on 1964 in Benghazi, Libya. Elfeitori served as the minister for Transportation and Communication on the executive office of the National Transitional Council, from 10 May 2011 to 22 November 2011. He was named Minister for Communications and Information Technology on 22 November 2011 by Abdurrahim El-Keib.

Suleiman Al-Fortia is a member of the Libyan National Transitional Council representing the city of Misrata. Fortia received his undergraduate degree from the University of Tripoli and a Doctor of Engineering in architecture from a British university. He has taught at King Faisal University for eight years. He has participated in delegations to France during talks where the anti-Gaddafi forces asked for weapons shipments. He also negotiated in person for aid efforts to help Misrata during the siege of Misrata.

Abdul Hafiz Ghoga is a Libyan human rights lawyer who rose to prominence as the spokesman for the National Transitional Council, a body formed in Benghazi during the 2011 Libyan civil war. On 23 March 2011, he became the vice chairman of the council, serving in that post until he resigned on 22 January 2012 after protests against him.

Fatima Hamroush is an ophthalmologist and Libyan politician.

Mahmoud Jibril el-Warfally, also transcribed Jabril or Jebril or Gebril, was a Libyan politician who served as the interim Prime Minister of Libya for seven and a half months during the overthrow of Muammar Gaddafi and the Libyan Civil War, chairing the executive board of the National Transitional Council (NTC) from 5 March to 23 October 2011. He also served as the Head of International Affairs. As of July 2012, Jibril was the head of one of the largest political parties in Libya, the National Forces Alliance.

Major General Osama al-Juwaili is a Libyan military officer who served as Minister of Defence in the government of Abdurrahim El-Keib, Libya's interim Prime Minister. Since the formation of the Government of National Accord (GNA) in 2015, al-Juwaili served it as a senior commander, since 2017 being the commander of the Western Military Zone. On 6 April 2019 he became the commander of the joint operations room, created by Prime Minister Fayez al-Sarraj to coordinate military operations since the start of the 2019 Western Libya offensive.

Abdurrahim Abdulhafiz El-Keib, PhD, was a Libyan politician, professor of electrical engineering, and entrepreneur who served as interim Prime Minister of Libya from 24 November 2011 to 14 November 2012. He was appointed to the position by the country's National Transitional Council on the understanding that he would be replaced when the General National Congress was elected and took power. Power was handed to the Congress on 8 August 2012, and the assembly appointed El-Keib's successor Ali Zeidan in October 2012.

Prince Ahmed Al-Zubair al-Senussi, also known as Zubeir Ahmed El-Sharif, is a Libyan member of the Senussi house and a member of the National Transitional Council representing political prisoners.

Ali Abdussalam Tarhouni is a Libyan economist and politician. Tarhouni served as the minister for oil and finance on the National Transitional Council, the provisional governing authority in Libya, from 23 March to 22 November 2011. He acted in the capacity of interim prime minister of Libya during the departure of outgoing incumbent Mahmoud Jibril from 23 October 2011 until Abdurrahim El-Keib was formally named to succeed Jibril on 31 October.

Fathi Terbil, also romanized as Fatih Turbel, is a Libyan lawyer and human rights activist and member of the National Transitional Council representing Libyan youth. He represents the relatives of over 1,000 prisoners killed by Libyan security forces in Abu Salim Prison in 1996. He is also the Youth and Sports Minister for the Interim Government.