
Krzysztof Zbigniew Bojko is a Polish diplomat, ambassador to Jordan (2012–2016) and Mongolia.

Adam Wojciech Burakowski is a Polish diplomat, political scientist and historian, since December 2017 serving as an ambassador of Poland to India.

Jan Stanisław Bury is a Polish political scientist and diplomat, since 2018 serving as an ambassador to Saudi Arabia.

Selim Chazbijewicz is a Polish political scientist, columnist, poet, since 2017 serving as an ambassador to Kazakhstan.

Bartosz Jan Cichocki is a Polish political scientist and historian, since 2019 serving as an ambasador to Ukraine.

Jacek Krzysztof Czaputowicz is a Polish politician and academic who served as Minister of Foreign Affairs of Poland from 9 January 2018 to 20 August 2020.

Sławomir Jan Dębski is a Polish historian, PhD (Hist.) who has served as director of Polish Institute of International Affairs from 2007 until 2010 and again since 2016. He previously headed The Centre for Polish-Russian Dialogue and Understanding (2011–2016), and was a member of the Polish-Russian Group for Difficult Matters. He was assistant professor of the Cardinal Stefan Wyszyński University in Warsaw (2007–2010) and Warsaw University (2010–2014).
Jarosław Jerzy Drozd is a Polish politologist and diplomat. He was serving as the Consul-General of Poland in Saint Petersburg (2007–2011) and Lviv (2011–2015).

Jadwiga Katarzyna Emilewicz is a Polish politician and political scientist. In 2020, she was Deputy Prime Minister of Poland. In 2019, she became Minister of Development, upon her three-year service as an undersecretary of state in the Ministry of Development, and from 2018 to 2019, she was Minister of Entrepreneurship and Technology in the government of Mateusz Morawiecki.
Adam Wacław Jelonek is the former Polish Ambassador to Malaysia, Brunei and the Philippines. He is a professor and head of department in the Department of Middle and Far East at the Jagiellonian University in Krakow. He is a sociologist and political scientist.

Paweł Robert Kowal is a former Polish politician and former Member of the European Parliament for Poland Together. During his time in the EP, he served as the Chairman of the EU-Ukraine Parliamentary Cooperation Committee in the European Parliament.

Jakub Radomir Kumoch is a Polish political scientist, journalist and diplomat, serving as an ambassador to Turkey and Switzerland (2016–2020).

Jerzy Karol Kurnatowski was a Polish lawyer, economist, academic, author, politician, public official, and political scientist. He has been awarded the Cross of Valour twice, the Legion of Honour, and the Order of the White Lion.

Piotr Leszek Łukasiewicz is a Polish diplomat, Colonel of the Polish Armed Forces, political scientist; ambassador to Afghanistan (2012–2014).

Włodzimierz Aleksander Marciniak is a Polish university teacher, political scientist and historian of Russia, as an ambasador to Russia (2016–2020).
Leszek Cezary Miller is a Polish political scientist and politician. He has served as a Member of the European Parliament (MEP) since July 2019.

Tomasz Młynarski is a Polish political scientist, since 2017 serving as an ambassador to France.

Piotr Ostaszewski is a Polish historian, political scientist and translator. Since 24 September 2017 serving as an ambassador to South Korea.

Mateusz Andrzej Piskorski is a Polish politics and publicist.

Zbigniew Rau is a Polish politician, lawyer, diplomat and the Minister of Foreign Affairs of Poland since 26 August 2020. He previously served as the voivode and governor of Łódź Voivodeship from 8 December 2015 to 11 November 2019.

Krzysztof Strzałka is a Polish political scientist and diplomat, since 2018 serving as an ambasador to Slovakia.

Tomasz Szatkowski is a Polish politician and political scientist, since 2019 serving as an ambassador to NATO. Specialist on national security domain, in particular defence and armaments policy.

Małgorzata Tarasiewicz is a Polish activist, politician, and political scientist. She was a coordinator of the Polish section of Amnesty International, where she was involved with efforts to establish the International Criminal Court. Tarasiewicz has been involved in the leadership of the Polish Green Party, and has run for public office as an independent.

Gertruda Uścińska is a Polish lawyer and political scientist. She is a Professor of Social Sciences at The University of Warsaw and the Polish Institute of Labor and Social Affairs in Warsaw (pl). Since 2016, Uścińska has been the President of Poland's Social Insurance Institution, which is the Polish state organization responsible for social insurance. She has also been an elected Chairwoman at the International Social Security Association.

Adam Wielomski is a Professor at the University of Natural Sciences and Humanities in Siedlce, where he teaches in the Institute of Social Sciences and Security of the Faculty of Humanities. Wielomski is the author and co-author of several books on Spanish and French counter-revolutionary political thought. He is also the editor-in-chief of quarterly journal Pro Fide Rege et Lege and a columnist for Najwyższy Czas!.

Wojciech Jacek Zajączkowski is a Polish diplomat and historian, since January 2018 serving as an ambassador of Poland to China.

Bartłomiej Aleksander Zdaniuk is a Polish political scientist who has served as an ambassador of Poland to Moldova since 18 October 2017.