
Cuimba is a town and municipality in Zaire Province in Angola. The municipality had a population of 69,194 in 2014.

Mbanza-Kongo, is the capital of Angola's northwestern Zaire Province with a population of 148,000 (2014). Mbanza Kongo was founded some time before the arrival of the Portuguese in 1483 and was the capital of the Kilukeni dynasty ruling at that time. The site was temporarily abandoned during civil wars in the 17th century. It lies close to Angola's border with the Democratic Republic of the Congo. It is located at around 6°16′0″S 14°15′0″E and sits on top of an impressive flat-topped mountain, sometimes called Mongo a Kaila because recent legends recall that the king created the clans of the kingdom and sent them out from there. In the valley to the south runs the Luezi River. In 2017, Mbanza Kongo was declared as a UNESCO World Heritage Site.

N'zeto is a town, with a population of 28,840, and a municipality located in the province of Zaire in Angola. During the Portuguese domain the town was called Ambrizete. The municipality has an estimated population of 56,199 (2019). It is served by N'zeto Airport.

Noqui is a town and municipality in Zaire Province in Angola. It is on the Congo River, just across the border from the city of Matadi in the Democratic Republic of the Congo. The municipality had a population of 23,880 in 2014.

Quimavongo is a town located in Zaire Province, Angola. As of 2009, it has 15,741 inhabitants.

Soyo is a city, with a population of 200,920, and a municipality, with a population of 227,175, located in the province of Zaire in Angola, at the mouth of the Congo river. Soyo recently became the largest oil-producing region in the country, with an estimate of 1,200,000 barrels per day (190,000 m3/d).

Tomboco is a town and municipality in Zaire Province in Angola. The municipality had a population of 46,025 in 2014.